PH extradants

The apparently simplest of procedures faces one with a choice of about four extractants. The commonest extractant is water, and the ratio we use is 10 ml soil:25 ml water, i.e. 1:2.5 v/v. Other ratios used by the Northeastern United States are 1:1 v/v, 1:1 w/v and 1:2 v/v soil/water (Delaware Cooperative Extension, 1995, Appendix). Some soils have a significant soluble salt content, which can affect the measured pH. The concentration of these salts in the soil varies with the season, with dry season pH values being lower than wet season ones. This is because salts such as sulphates and nitrates, which lower pH, accumulate in dry periods and are leached away in rainy periods. To overcome this effect, a 1 M KCl extractant was first used. The pH values so obtained are 1.5-2.0 units less than those with water extractant, and are also affected by variations in the soil:extractant ratio. It is still used to assess the aluminium status of the soil. Values below pH 5 indicate significant amounts of Al, and if very much lower than 5, almost all the acidity is in the form of Al (USDA, 1996, p. 149). The aluminium acts by displacing hydrogen ions from the exchange sites on the surface of clay and humus particles to increase the acidity by raising the hydrogen ion (H+) concentration.

It was later proposed that more suitable extractants to overcome, and also measure, the salt effects which displace hydrogen ions in a seasonal manner would be either 0.1 M KCl or 0.01 M CaCl2, with the latter being more widely used (Schofield and Taylor, 1955).

The effect on mineral soils with a permanent negative charge, or on organic soils with a negative charge which varies with pH, is to displace H+ and lower the measured pH by about 0.5 units compared with water extractant. The effect on mineral soils dominated by sesquioxides, kaolinite and allo-phane with variable charge is that the salt causes adsorption of H+ onto reactive sites, raising the pH by about 0.5 units (Rowell, 1994, p. 161). The difference in pH between water and salt solution extracts is known as the salt effect, and given the symbol A pH. Thus,

A pH = soil pH in salt solution - soil pH in water and A pH values are positive for soils with a net positive charge, and negative for soils with a net negative charge, with magnitude proportional to charge.

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